期刊

Nanoscale

标题

Alkynyl-protected silver nanoclusters featuring an anticuboctahedral kernel

作者

Shang-Fu Yuan, Pei Li, Qing Tang, Xian-Kai Wan, Zi-Ang Nan, De-en Jiang, Quan-Ming Wang

摘要

Two unique silver nanoclusters protected by alkynyl and diphosphine ligands have been synthesized. Single crystal structural determination reveals that they have a centered anticuboctahedral Ag13kernel. Such a kernel is observed for the first time in a coinage metal nanocluster. This work offers new insights into the fact that the PhCC ligand represents a new direction in synthesizing novel metal nanoclusters.

原文链接

http://pubs.rsc.org/en/content/articlelanding/2017/nr/c7nr02687k#!divAbstract