Asymmetric α-Photoalkylation of β-Ketocarbonyls by Primary Amine Catalysis: Facile Access to Acyclic All-Carbon Quaternary Stereocenters

产品简述

期刊

JACS


标题

Asymmetric α-Photoalkylation of β-Ketocarbonyls by Primary Amine Catalysis: Facile Access to Acyclic All-Carbon Quaternary Stereocenters


作者

Yunbo Zhu, Long Zhang, and Sanzhong Luo*


摘要

Merging photoredox catalysis and chiral primary amine catalysis enables the coupling of phenacyl radicals and enamine carbonyls to generate acyclic all-carbon quaternary centers with excellent enantioselectivity under visible light irradiation. See Luo and co-workers, p 14642. 


原文链接

http://pubs.acs.org/toc/jacsat/136/42

2017年02月08日

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