Merging [2+2] Cycloaddition with Radical 1,4-Addition: Metal-Free Access to Functionalized Cyclobuta[a]naphthalen-4-ols

产品简述

期刊

Angewandte Chemie, International Edition


标题

Merging [2+2] Cycloaddition with Radical 1,4-Addition: Metal-Free Access to Functionalized Cyclobuta[a]naphthalen-4-ols


作者

Feng Liu, Jia-Yin Wang,  Peng Zhou,  Guigen Li,  Wen-Juan Hao,  Shu-Jiang Tu,  Bo Jiang


摘要

A merger of a metal-free [2+2] cycloaddition and an S-centered radical induced 1,4-addition of benzene-linked allene-ynes has been established. In their Communication on page 15570 ff., B. Jiang et al. describe the utility of their reaction for accessing functionalized cyclobuta[a]naphthalen-4-ols. The picture shows the eagles bringing together the components of the reaction.


原文链接

http://onlinelibrary.wiley.com/doi/10.1002/anie.201710882/full



2017年12月13日

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