Synthesis and Mechanistic Study of Cyclic Oxoguanidines via Zn(OTf)2-Catalyzed Guanylation/Amidation from Readily Available Amino Acid Esters and Carbodiimides (Chem. Eur. J. 29/2015) (page 10580)

产品简述

期刊
Chemistry - A European Journal


标题
Synthesis and Mechanistic Study of Cyclic Oxoguanidines via Zn(OTf)2-Catalyzed Guanylation/Amidation from Readily Available Amino Acid Esters and Carbodiimides (Chem. Eur. J. 29/2015) (page 10580)


作者
Yue Chi, Ling Xu, Shanshan Du, Haihan Yan, Prof. Dr. Wen-Xiong Zhang and Prof. Dr. Zhenfeng Xi


摘要
Cheap and cheerful: The Zn(OTf)2-catalyzed guanylation/amidation from readily available amino acid esters and carbodiimides has been achieved to efficiently provide various cyclic oxoguanidines (see scheme). It is the first time that an ammonium salt has been used in the guanylation reaction. Application of cyclic oxoguanidines is explored to provide conjugated heterocyclic compounds through oxidative C[BOND]N formation or aldol reactions.


原文链接
http://onlinelibrary.wiley.com/doi/10.1002/chem.201500573/abstract


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